Highly Active Binuclear Neutral Nickel(II) Catalysts Affording High Molecular Weight Polyethylene

Highly Active Binuclear Neutral Nickel(II) Catalysts Affording High Molecular Weight Polyethylene

A series of new binuclear neutral κ-N,O-chelated Ni(II) complexes [(H2C)n{[(2,6-R2-4-yl-C6H2)NdC(H)-(3,5-I2-2-O-C6H2)-κ-N,O]Ni(CH3)(pyridine)}2] (R ) iPr, 3,5-(CF3)2C6H3; n ) 0, 1) are reported. The complexes are single-component catalyst precursors for ethylene polymerization. Catalyst activities exceed those of mononuclear analogues studied substantially. With 3.4 × 10 TO h, high molecular we...

Synthesis of high molecular weight polyethylene using FI catalyst

A FI Zr-based catalyst of bis[N-(3,5-dicumylsalicylidene)-2′,6′­diisopropylanilinato]zirconium(IV) dichloride was prepared and used for polymerization of ethylene. The effects of reaction conditions on the polymerization were examined in detail. The increase in ethylene pressure and rise in polymerization temperature up to 35 oC were favorable for catalyst/MAO to raise the catalytic activity as...

Wear of Ultra High Molecular Weight Polyethylene

synthesis of high molecular weight polyethylene using fi catalyst

a fi zr-based catalyst of bis[n-(3,5-dicumylsalicylidene)-2′,6′­diisopropylanilinato]zirconium(iv) dichloride was prepared and used for polymerization of ethylene. the effects of reaction conditions on the polymerization were examined in detail. the increase in ethylene pressure and rise in polymerization temperature up to 35 oc were favorable for catalyst/mao to raise the catalytic activity as...

Properties of crosslinked ultra-high-molecular-weight polyethylene.

Substantially reducing the rate of generation of wear particles at the surfaces of ultra-high-molecular-weight polyethylene (UHMWPE) orthopedic implant bearing components, in vivo, is widely regarded as one of the most formidable challenges in modern arthroplasty. In the light of this, much research attention has been paid to the myriad of endogenous and exogenous factors that have been postula...